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Question

During the electrolysis of cupric chloride, the reactions occurring at electrodes are


A

At the anode:
Cu2++2eCu(s)

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B

At the cathode:
2ClCl2(g)+2e

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C

At the cathode:
Cu2++2eCu(s)

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D

At the anode:
2ClCl2(g)+2e

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Solution

The correct options are
C

At the cathode:
Cu2++2eCu(s)


D

At the anode:
2ClCl2(g)+2e


A little of cupric chloride is taken in a beaker. In the same beaker, two graphite rods are dipped and connected to 4.5 V battery. When electricity is passed through CuCl2 solution, Cu and Cl2 are obtained.

Overall reaction: CuCl2(aq)Cu(s)+Cl2(g)

Reduction at the cathode: Cu2++2eCu(s)

Oxidation at the anode: 2ClCl2(g)+2e


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