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Question

During the purification of copper by electrolysis:

A
the anode used is made of copper ore
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B
pure copper is deposited on the cathode
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C
the impurities such as Ag, Au present in solution as ions
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D
concentration of CuSO4 solution remains constant during dissolution of Cu
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Solution

The correct options are
A pure copper is deposited on the cathode
C concentration of CuSO4 solution remains constant during dissolution of Cu
D the anode used is made of copper ore
Anode : - Impure copper or crude copper.
Cathode : Pure copper
Electrolyte : 15% CuSO4 solution +5% H2SO4
When electric current is passed through the electrolyte, the angle anode gradually dissolve and pure copper is deposited on the cathode which gradually grow in size. The impurities like, Fe,Zn,Ni, etc, dissolved in the solution as while gold, silver, platinum settle down the anode as anode mud.
Reaction Occurring are as follows.
CuSO4Cu+2+SO24; At anode : Cu2eCu+2
Cathode : Cu+2+2eCu

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