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Question

E value of Mg2+|Mg,Zn2+|Zn and Fe2+|Fe are – 2.37 V, - 0.76 V and 0.44 V respectively. Which of the following is correct?


A

Mg2+ Oxidises Fe to Fe2+

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B

Zn Oxidises Fe2+ to Fe

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C

Zn reduces Mg2+ to Mg

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D

Zn reduces Fe2+ to Fe

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Solution

The correct option is D

Zn reduces Fe2+ to Fe


Reduction potential values : iron ions > zinc ions > magnesium ions.

The idea is that both the reactions must form a postive cell potential value. For this, the species getting reduced is at the cathode and the other one at the anode. The anode is where oxidation happens, so the sign needs to be reversed as we have reduction potential values here.

This means that iron ions are most likely to get reduced in this setup due to their positive value. Zinc and magesium metals can reduce iron ions. Option D fits.


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