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Byju's Answer
Standard XII
Chemistry
Equilibrium Constant from Nernst Equation
Eocell for th...
Question
E
o
c
e
l
l
for the reaction,
2
H
2
O
→
H
3
O
+
+
O
H
−
at
25
o
C is
−
0.8277
V
.
The equilibrium constant for the reaction is:
A
10
−
14
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B
10
−
23
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C
10
−
7
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D
10
−
21
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Solution
The correct option is
A
10
−
14
Given reaction,
2
H
2
O
→
H
3
O
+
+
O
H
−
We know a relation,
l
o
g
K
=
E
0
c
e
l
l
×
n
0.0591
l
o
g
K
=
−
0.8277
×
1
0.0591
=
−
14
⇒
K
=
10
−
14
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0
Similar questions
Q.
For the reaction:
N
H
+
4
+
2
H
2
O
⇌
N
H
4
O
H
+
H
3
O
+
K
1
=
5.56
×
10
−
10
H
2
O
+
H
2
O
⇌
H
3
O
+
+
O
H
−
K
2
=
1
×
10
−
14
Hence
K
3
of the reaction:
N
H
4
O
H
⇌
N
H
+
4
+
O
H
−
is:
Q.
The standard reduction potential at
25
o
C for the reduction of water
2
H
2
O
+
2
e
⇌
H
2
+
2
O
H
is
−
0.8277
volt. Calculate the equilibrium constant for the reaction
2
H
2
O
⇌
H
3
O
+
+
O
H
at
25
o
C.(Answer up to 2 decimal places.)
Q.
The
K
w
for water for the equillibrium,
2
H
2
O
⇌
H
3
O
+
O
H
−
changes from
10
−
14
at
25
∘
C
to
9.62
×
10
−
14
at
60
∘
C
.
Calculate the
p
H
and nature at
60
∘
C
Q.
The standard reduction potential at
25
∘
C
of the reaction
2
H
2
O
+
2
e
−
→
H
2
+
2
O
H
−
is
−
0.8277
v
o
l
t
. Calculate the equilibrium constant for the reaction,
2
H
2
O
⇌
H
3
O
+
+
O
H
−
at
25
∘
C
.
Q.
2
H
2
O
⇌
H
3
O
+
+
O
H
−
,
K
w
=
1
×
10
−
14
at
25
∘
C
. Hence,
K
a
is:
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