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Byju's Answer
Standard XII
Chemistry
Nernst Equation
E⊖ for Cr3+ +...
Question
E
⊖
f
o
r
C
r
3
+
+
3
e
−
→
C
r
a
n
d
C
r
3
+
+
e
−
→
C
r
2
+
are
−
0.74
V
and
−
0.40
V
, respectively.
E
⊖
for the reaction is:
C
r
+
2
+
2
e
−
→
C
r
A
−
0.91
V
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B
+
0.91
V
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C
-
1.14
V
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D
+
0.34
V
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Solution
The correct option is
A
−
0.91
V
C
r
3
+
+
3
e
−
→
C
r
;
C
r
3
+
+
e
−
→
C
r
2
+
;
C
r
2
+
+
2
e
−
→
C
r
;
E
⊖
3
=
n
1
E
⊖
1
−
n
2
E
⊖
2
n
3
=
[
3
×
(
−
0.74
)
]
−
[
(
−
1
)
×
(
−
40
)
]
2
=
−
0.91
V
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0
Similar questions
Q.
A cell is to be constructed to show a redox change:
C
r
+
2
C
r
3
+
⇌
3
C
r
2
+
. The number of cells with different
E
⊖
and n but same value of
Δ
G
⊖
can be made:
(Given:
E
⊖
C
r
3
+
|
C
r
2
+
=
−
0.40
V
,
E
⊖
C
r
3
+
|
C
r
=
−
0.74
V
,
a
n
d
E
⊖
C
r
2
+
|
C
r
=
−
0.91
V
Q.
What will be the
E
0
value for the given half cell reaction?
C
r
2
+
(
a
q
)
+
2
e
−
→
C
r
(
s
)
Given:
E
0
value for the half cell reaction,
C
r
3
+
(
a
q
)
+
e
−
→
C
r
2
+
(
a
q
)
;
E
0
=
−
0.41
V
C
r
3
+
(
a
q
)
+
3
e
−
→
C
r
(
s
)
;
E
0
=
−
0.74
V
Q.
The value of E for elements are as follows:
F
e
+
2
+
2
e
→
F
e
;
E
o
=
0.44
V
F
e
+
3
+
1
e
→
F
e
+
2
;
E
o
=
+
0.77
V
S
n
+
4
+
2
e
→
S
n
+
2
;
E
o
=
+
0.13
V
I
2
+
2
e
→
2
I
;
E
o
=
+
0.54
V
C
r
3
+
+
3
e
→
C
r
;
E
o
=
0.74
V
Based on the above data correct statements are:
Q.
The standard reduction potentials for the following reaction are
Z
n
2
+
+
2
e
−
→
Z
n
;
(
−
0.762
V
)
C
r
3
+
+
3
e
−
→
C
r
;
(
−
0.74
V
)
2
H
+
+
2
e
−
→
H
2
;
(
0.0
V
)
F
e
3
+
+
e
−
→
F
e
2
+
;
(
0.77
V
)
The reducing powers of these species are in the order:
Q.
Given,
E
∘
C
r
3
+
/
C
r
=
−
0.72
V
,
E
∘
F
e
2
+
/
F
e
=
−
0.42
V
.
The potential for the cell
C
r
|
C
r
3
+
(
0.1
M
)
|
|
F
e
2
+
(
0.01
M
)
|
F
e
is:
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