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Question

Each oxy-acid contains at least one XOH unit (X is non-metal). The H-atom of XOH unit is ionisable and the number of OH groups directly attach to non-metal decides the basicity Of oxy-acid.

Which of the following oxyanions of pyro acid has different oxidation state of central metal atoms?

A
S3O26
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B
Si2O67
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C
S2O25
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D
None
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Solution

The correct option is C S2O25

(a) S3O26 have +5 oxidation state on both S central atoms.
(b) Si2O67 have +6 oxidation state on both S central atoms.
(c) S2O25 have +5 oxidation state on one S central atom and +3 on another S central atom.

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