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Question

EAN of metal in any monometallic carbonyl complex remains same when:-

A
Three carbonyls (CO) ligands are replaced by two nitrosyl (NO) ligands
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B
Two carbonyls ligands are replaced by three nitrosyl ligands
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C
All the carbonyls ligands are replaced by all nitrosyl ligands
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D
One carbonyls ligands is replaced by three nitrosyl ditrosy ligands
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Solution

The correct option is C All the carbonyls ligands are replaced by all nitrosyl ligands
Because CO and NO, both of them forms 1 coordinate bond at a time and both are neutral ligands. Hence EAN will remain same when all the carbonyl ligands are replaced by all nitrosyl ligands.
Answer is option C.

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