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Question

Electra has mastered the basics of Nernst equation. She is now studying equilibrium constants relation with Nernst equation.

Electra was performing experiments with Nernst with a Daniel Cell. She noticed that when the reaction reaches equilibrium, the cell potential goes to 0.

She asked Nernst why this happened. His reply was



A
Because there is no displacement reaction
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B
Because there is change in temperature
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C
Because there is no change in concentration of Cu2+ and Zn2+
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D
Because all the ions have been depleted.
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Solution

The correct option is C Because there is no change in concentration of Cu2+ and Zn2+

The first thing we need to understand here is that the reaction that is taking place here i.e the oxidation of Zn

Zn Zn2+ + 2e-

Or the reduction of Cu

Cu2+ + 2e- Cu

These reactions don’t really stop at equilibrium, because it is a dynamic equilibrium.

But the change in concentration of Cu2+ and Zn2+ don't change in the net reaction. This is the reason for no electrode potential because there is no net electron transfer.

Option a and b don’t make any sense in this context.

Option d is false because ions won’t be depleted completely.


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