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Question

Electrolysis of sea-water produces Cl2(g) at the anode by the oxidation of Cl (aq) ions. What volume of the gas will be produced at STP by current of 1.50 A applied for 90.0 minutes?

A
0.313 L
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B
0.548 L
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C
0.94 L
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D
0.470 L
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Solution

The correct option is B 0.94 L
Apply farrady law
W=E*i*t/96500
Where W= amount of substance produced
E= Molecular weight/ n- factor
Put the values
W= 71*1.5*90*60/(2*96500)
W= 2.97 grams
Moles = 2.97/71=0.042
1mole of Cl2 containing 22.4 L volume.
Then,
0.042 mole of Cl2 containing 22.4*0.042 = 0.94L volume.


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