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Question

Electrolytic reduction of nitrobenzene in weakly acidic medium gives:

A
aniline
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B
nitrosobenzene
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C
N-phenylhydroxylamine
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D
P-hydroxyaniline
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Solution

The correct option is A aniline
Electrolytic reduction of nitrobenzene in a weakly acidic medium gives aniline but in a strongly acidic medium, it gives p-aminophenol through the acid-catalyzed rearrangement of the initially formed phenylhydroxylamine.
500698_471137_ans_e80b9f9e9c214577a60b1f8f67a069b9.png

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