Electrolytic refining always involves low temperatures and aqueous solutions – True or False?
False
Although it seems that electrolytic refining involves lower temperatures, this is not true. For instance, Crude Aluminum is refined using electrolysis which involves high temperatures to melt the electrolyte (Cryolite + CaF2 saturated with Al2O3). Also, the extraction of Aluminum from Al2O3 is in itself a high temperature process (happens between 950–1050∘C)
In both these cases, the medium is non-aqueous.