Electromagnetic radiation of wavelength 663nm is just sufficient to ionise the atom of metal A. The ionization energy of metal A in kJmol−1 is (Rounded - off to the nearest integer)
[h=6.63×10−34Js,c=3.00×108ms−1,NA=6.02×1023mol−1]
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Solution
Ionisation energy of an atom of metal A = Quantum energy of radiation of wavelength 663nm =6.63×10−34×3×108×6.02×1023663×10−9×1000J=3×10−19J Ionisation energy per mol =3×10−19×10−3×6.02×1023 =180.6kJmol−1=181kJmol−1