The correct option is B 1s2,2s22p6,3s23p63d5
1s2,2s22p6,3s23p63d6,4s2 is the correct electronic configuration of Fe atom. When iron turns into Ferric ion Fe3+, it looses three electrons and becomes positive ion therefore the 3+ sign.
Electrons are lost from the outermost orbit first i.e from 4s2, 2 electrons are lost and then from 3d6, 1 electron is lost therefore the configuration for ion Fe3+ becomes 1s2,2s22p6,3s23p63d5