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Question

Electronic configuration of four elements A, B, C, and D are given below
A. 1s22s22p6 B. 1s22s22p4 C. 1s22s22p63s1
D. 1s22s22p5
Whilch of the following is the correct order of increasing tendency to gain electron?
(a) A < C <B <D (b) A < B < C < D (c) D <B < C < A (d) D < A < B <C

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Solution

Electronic configuration of elements indicate that A is a noble gas (i.e. ne)I B is oxygen (group 16) , C is sodium metal (group 1 ) and D is fluorine (group 17).
(i) Noble gases have no tendency to gain electrons since all their orbitals are completely filled. Thus element a has the least electron gain enthalpy
(ii) Since element D ahs one electron less and element B has Two electrons less than the corresponding noble gas configuration, hence element D has the highest electron gain enthalpy followed by element B
(iii) Since, element C has one electron in the s- orbital and hence needs one more electron to complete it, therefore, electron gain enthalpy of C is less than that of element B. Combining all the facts given above the electron gain enthalples of the four elements increase in the order A < C< B< D.


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