The correct option is A Phosphorous
Sodium and potassium form basic oxides and hence they would turn red litmus blue.
Sulphur is not very reactive. It requires constant burning to form its oxides.
So, phosphorous reacts with oxygen to form phosphorous pentoxide.
P4+5O2→P4O10
P4O10+6H2O→4H3PO4
Phosphoric acid changes blue litmus red.