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Question

Elements of group 14

(a) exhibit oxidation state of +4 only

(b) exhibit oxidation state of +2 and +4

(c) form M2– and M4+ ion

(d) form M2+ and M4+ ions

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Solution

(b)The elements of group 14 have 4 valence electrons. Therefore, the oxidation state of the group is +4. However, as a result of the inert pair effect, the lower oxidation state becomes more and more stable and the higher oxidation state becomes less stable. Therefore, this group exhibits +4 and +2 oxidation states.

Group 14 element

Oxidation state

C

+4

Si

+4

Ge, Sn, Pb

+2, +4


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