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Question

Elements X, Y and Z have valencies 1, 3 and 4 respectively. Formula unit masses of their oxides are 62, 102 and 64 respectively. If atomic mass of Z is divided by the difference in atomic masses of X and Y then value obtained is the atomic number of which of the following elements?

A
Carbon
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B
Nitrogen
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C
Oxygen
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D
Fluorine
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Solution

The correct option is B Oxygen
Element X is Na.Its oxide is Na2O and mass will be = 23 + 23 + 16 = 62
Element Y is Al and oxide is Al2O3 and mass will be 27+ 27 + {16*3} = 102.
Element Z is sulphur and oxide is SO2 and mass = 32 + {2*16} = 64
Difference in atomic mass of X and Y = 4.
32/4 = 8 = Oxygen's atomic no.

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