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Question

Energy barrier between staggered and eclipsed ethane is :

A
6.0 kcal/mole
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B
3.0 kcal/mole
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C
2.0 kcal/mole
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D
4.0 cal/mole
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Solution

The correct option is B 3.0 kcal/mole
The eclipsed structure is important not because it is highly populated , but because its energy relative to the staggered structure defines how much energy is required to complete a rotation in ethane.
This is called the energy barrier to rotation, and it is about 3 kcal/mol.

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