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Question

Energy of activation is lower for reaction :

A
RCH2OH2RCH2
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B
R2CHOH2R2CH
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C
R3COH2R3C
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D
all have same Eact
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Solution

The correct option is B R3COH2R3C
Formation of a more stable carbocation result in lower activation energy and faster ionization. The stability of carbocations increases as we go from primary to secondary to tertiary carbons, due to carbons (alkyl groups in particular) as being “electron-releasing” groups through inductive effects. Therefore option C is the correct answer.

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