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Question

Enthalpies of formation of CO(g), CO2(g), N2O(g) and N2O4(g) are –110 kJ mol–1, – 393 kJ mol–1, 81 kJ mol–1 and 9.7 kJ mol–1 respectively. Find the value of ΔrH for the reaction:

N2O4(g) + 3CO(g) N2O(g) + 3CO2(g)

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Solution

ΔrH for a reaction is defined as the difference between ΔfH value of products and ΔfH value of reactants.

For the given reaction,

N2O4(g) + 3CO(g) N2O(g) + 3CO2(g)

Substituting the values of ΔfH for N2O, CO2, N2O4, and CO from the question, we get:

Hence, the value of ΔrH for the reaction is.


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