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Question

Enthalpies of formation of CO(g), CO2(g) N2O(g) and N2O4(g) are 110,393.81 and 9.7kJ mol1 respectively. Find the value of rH for the reaction :

N2O4(g)+3CO(g)N2O(g)+3CO2(g)

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Solution

The balanced chemical reaction is N2O4(g)+3CO(g)N2O(g)+3CO2(g)

The enthalpy change for the reaction is,
ΔrH=ΔfH[N2O(g)]+3ΔfH[CO2(g)][ΔfHN2O49g)+3ΔfH[CO(g)]]
ΔrH=81+3(393)[9.7+3(110)]
ΔrH=777.7kJ/mol
Hence, the enthalpy change for the reaction is 777.7kJ/mol.

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