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Question

Enthalpy of atomisation of a diamond is 600 kJ/mol.
C(diamond)C(g).
Using this data the bond energy of C-C bond was found to be x×102 kJ/mol where x is an interger between 0 to 9. Value of x is

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Solution

In producing one mole of C(g).
number CC bonds broken =12×4×NA=2NA
So 2NACC bonds contain energy equal to energy of atomisation.
but energy of atomisation is 600 kJ/mol.

comparing the values,
2NAϵCC=600 kJ
2NAϵCC=300 kJNA
ϵCC=300 kJ/mol

comparing this to question,
clearly, x=3


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