Enthalpy of neutralization of acetic acid and sodium hydroxide is -55.4 kJ/mol. The enthalpy of ionization of acetic acid is
A
- 5.54 kJ/mol
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B
+ 5.54 kJ/mol
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C
- 1.7 kJ/mol
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D
+ 1.7 kJ/mol
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Solution
The correct option is D + 1.7 kJ/mol Maximum ΔHi value possible (for strong acid and strong base)=57.1 kJ/mol ∴ΔHiofabovecombinationis=57.1−55.4=1.7kJ/mol