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Question

Enthalpy of neutralization of the reaction between CH3COOH(aq) and NaOH(aq) is 13.2 Kcal eq1 and that of reaction between H2SO4(aq) and KOH(aq) is 13.7 Kcal eq1. The enthalpy of dissociation of CH3COOH(aq) is:

A
0.5 kcal eq1
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B
+0.5 kcal eq1
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C
26.9 kcal eq1
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D
+13.45 kcal eq1
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Solution

The correct option is B +0.5 kcal eq1

Dissociation enthalpy of CH3COOH = 13.713.2 = 0.5 kcal eq1

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