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Question

Entropy change (ΔS) for the vaporization of water at 100oC
(Given ΔH(vap)=40.7kJ/mol)

A
40.7J/Kmol
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B
109.1J/Kmol
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C
10.91J/Kmol
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D
90.11J/Kmol
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Solution

The correct option is A 109.1J/Kmol
We know that
q=ΔH at constant pressure
since, vaporization at 100oC is reversible
ΔG=0 and
ΔS=qrevT=0.47×103373.1K=109.1J/Kmol

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