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Question

Equal masses of ethene and butene have their total translational kinetic energy in the ratio 2:1, then their absolute temperatures are in the ratio :

A
2:1
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B
1:2
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C
2:3
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D
1:1
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Solution

The correct option is D 1:1
The expression for the translational kinetic energy is E=32×massmolecularweightRTe.
The expression for the translational kinetic energy of ethene is Ee=32×M28RTe.
The expression for the translational kinetic energy of butene is Eb=32×M56RTb.

Dividing both equation,

EeEb=5628TeTb.

21=5628TeTb.

TeTb=11.

Thus, their absolute temperatures are in the ratio 1:1.

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