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Question

Equal moles of NO2(g) and NO(g) are to be placed in a container to produce N2O according to the reaction,


NO2+NON2O+O2; Kc=0.914

How many moles of NO2 and NO be placed in the 5.0 L container to have an equilibrium concentration of N2O to be 0.05 M?

A
0.511
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B
0.1023
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C
0.0526
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D
0.2046
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Solution

The correct option is B 0.511
NO2 + NO N2O + O2
Intially x x 0 0
At eq. xy5 xy5 y5 y5

Given : [N2O]=0.05 M
y5=0.05
y=0.25 moles

Kc=[N2O][O2][NO2][NO]

0.914=0.25×0.25(x0.25)2

$x = 0.511\ moles$

Hence, Moles of NO2 = Moles of NO=0.511 moles

Therefore, option A is correct.

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