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Question

Equivalent conductance of BaCl2,H2SO4 and HCl are x1,x2 and x3Scm2equiv1 at infinite dilution.If specific conductance of saturated BaSO4 solution is of yScm1 then Ksp of BaSO4 is:

A
103y2(x1+x22x3)
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B
106y24(x1+x22x3)2
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C
106y22(x1+x2x3)2
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D
x1+x22x3106y2
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Solution

The correct option is A 103y2(x1+x22x3)
Λeq(BaSO4)=Λeq(BaCl2)+Λeq(H2SO4)2Λeq(HCl)
=(x1+x22x3)Scm2eq1
Λeq=K×1000NN=(y×103x1+x22x3)(nf=2)
M={y×1032(x1+x22x3)}
Ksp=(M)2={y2×1064(x1+x22x3)2}

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