Equivalent conductance of BaCl2,H2SO4 and HCl are x1,x2 and x3Scm2equiv−1 at infinite dilution.If specific conductance of saturated BaSO4 solution is of yScm1 then Ksp of BaSO4 is:
A
103y2(x1+x2−2x3)
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B
106y24(x1+x2−2x3)2
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C
106y22(x1+x2−x3)2
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D
x1+x2−2x3106y2
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Solution
The correct option is A103y2(x1+x2−2x3) Λeq(BaSO4)=Λeq(BaCl2)+Λeq(H2SO4)−2Λeq(HCl)