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Question

Ethyl alcohol and propane have nearly equal molecular weights. But, the former is a liquid with high boiling point and the latter is a gas with low boiling point. Give reason.

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Solution

Alcohols have higher boiling points than alkanes of same molecules mass because alcohols (OH) have hydroxyl groups which involve in hydrogen bonding.As the intermolecular forces are relatively high in hydrogen bonding,ethylalcohol has higher boiling point than propane.

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