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Question

Exactly 3.0 g of carbon was burned to CO2 in copper calorimeter. The mass of calorimeter is 1.5kg and the mass of water in calorimeter is 2kg. The initial temperature was 20oC and the final temperature was 31.3oC. If specific heat of copper is 0.0826cal/gK, the heat value to closest integer of carbon in kcal/g is

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Solution

The quantity of heat transferred
q=mwater×Swater×ΔTwater+mcopper×Scopper×ΔTcopper
q=2000×1×11.3+1500×0.0826×11.3
q=22600+1400=24000cal=24kcal
This heat is for 3 g of carbon.
For 1 g of carbon, the heat transferred will be 24kcal3g=8kcal/g.

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