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Question

Expalin the following:
The Eocu21/cu for copper metal is positive (+0.34), unlike the remaining members of the first transition series

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Solution

E(M2+/M) value of a metal depends on the energy changes involved in the following:
(1) Sublimation
M(s)Mg
(2) Ionization
M2gM2+g
(3) Hydration
M2(g)M2+(aq)
As copper has a high energy of atomization and low hydration energy. Hence, the E(M2+/M) value of copper is positive.

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