Experimentally it was found that a metal oxide has formula M0.98O. Metal M is present as M2+ and M3+ in its oxide. % of the metal which exists as M3+ would be :
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Solution
Average oxidation number of M=+20098 (lies between 2 and 3). Let % of M2+ be α and of M3+ be b. or, 2×a+(100−a)×3100=2.04(∵a+b=100) ∴2a+300−3a=20098 ∴+a=300−2.04×100=300−204=96 Thus, M2+ = 96% and M3+ = 4%.