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Question

Experimentally it was found that a metal oxide has formula M0.98O. Metal M is present as M2+ and M3+ in its oxide. % of the metal which exists as M3+ would be :

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Solution

Average oxidation number of M=+20098 (lies between 2 and 3).
Let % of M2+ be α and of M3+ be b.
or, 2×a+(100a)×3100=2.04(a+b=100)
2a+3003a=20098
+a=3002.04×100 =300204=96
Thus, M2+ = 96% and M3+ = 4%.

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