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Question

Explain Carbyl amine reaction.

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Solution

Hoffmann's carbylamines test/ Isocyanide test:
Aliphatic or aromatic primary amines on heating with chloroform and alcoholic KOH give foul smelling alkyl isocyanides or carbylamines. This test is not given by secondary or tertiary amines.
PhNH2+CHCl3+3KOHΔPhNC+3KCl+3H2O

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