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Question

Explain giving reasons, which of the following sets of quantum numbers are not possible.
i) n = 0, 1 = 0, m = 0 , s = +1/2
ii) n = 1, | = 0, m = 0, s = -1/2
iii) n = 3, | = 1, m = 0, s = + 1/2
iv) n = 2, | = 1, m = 0, s = - 1/2
v) n = 3, | = 3, m = -3, s = + 1/2
vi) n = 3, | = 1 , m = 0, s = + 1/2

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Solution

(i) n=0,l=0,m=0,s=+1/2
Not possible
(ii) n=1,l=0,m=0,s=1/2
1s Possible
(iii) n=3,l=1,m=0,s=+1/2
3p Possible
(iv) n=2,l=1,m=0,s=1/2
2p Possible
(v) n=3,l=3,m=3,s=+1/2
3d Possible
(vi) n=3,l=1,m=0,s=+1/2
3p Possible

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