Explain, how is the electronegativity of carbon atoms related to their state of hybridisation in an organic compound?
Electronegativity of carbon atoms increases as the percentage of the s-character in their state of hybridisation increases. This is because s-electrons are more strongly attracted to the nucleus than p-electrons.
Hybridisation | Percentage of s-character | Percentage of p-character |
sp | 50 | 50 |
sp2 | 33 | 67 |
sp3 | 25 | 75 |
Therefore, order of electronegativity will be: sp3<sp2<sp.