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Question

Explain, how is the electronegativity of carbon atoms related to their state of hybridisation in an organic compound?


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Solution

Electronegativity of carbon atoms increases as the percentage of the s-character in their state of hybridisation increases. This is because s-electrons are more strongly attracted to the nucleus than p-electrons.

Hybridisation Percentage of s-character Percentage of p-character
sp 50 50
sp2 33 67
sp3 25 75

Therefore, order of electronegativity will be: sp3<sp2<sp.


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