Question

Explain structures of diborane and boric acid.

Answer 1

(a) Diborane

B₂H₆ is an electron-deficient compound. B₂H₆ has only 12 electrons – 6 e^– from 6 H atoms and 3 e^– each from 2 B atoms. Thus, after combining with 3 H atoms, none of the boron atoms has any electrons left. X-ray diffraction studies have shown the structure of diborane as:

2 boron and 4 terminal hydrogen atoms (H_t) lie in one plane, while the other two bridging hydrogen atoms (H_b) lie in a plane perpendicular to the plane of boron atoms. Again, of the two bridging hydrogen atoms, one H atom lies above the plane and the other lies below the plane. The terminal bonds are regular two-centre two-electron (2c – 2e^–) bonds, while the two bridging (B–H–B) bonds are three-centre two-electron (3c – 2e^–) bonds.

(b) Boric acid

Boric acid has a layered structure. Each planar BO₃ unit is linked to one another through H atoms. The H atoms form a covalent bond with a BO₃ unit, while a hydrogen bond is formed with another BO₃ unit. In the given figure, the dotted lines represent hydrogen bonds.