Explain the following
(i) Electronegativity of elements increase on moving from left to right in the periodic table.
(ii) Ionisation enthalpy decreases in a group from top to bottom.
Explain the following
(i) Electronegativity of elements increase on moving from left to right in the periodic table.
(ii) Ionisation enthalpy decreases in a group from top to bottom.
(i)
Across the period, the nuclear charge increases and the atomic radius decreases As. A result, the tendency of the atom of an element to attract the shared pair of electrons towards itself increases and hence the electronegativity of the element increases e.g., electronegativity of the elements of the 2nd period increases regularly from left to right as follows Li (1,0), Be (1.5), B (2,0) C (2.5), N (3.0), O (3.5) and
(ii)
The lonisation enthalpy decreases regularly as we move from top to bottom, as explained below.
(a). On moving down a group from top to bottom, the atomic size increases gradually due to the addition of a new principal energy shell at each succeeding element. As a result, the distance between the nucleus and the valence shell increases.
In other words, the force the ionisation enthalpy should decrease.
(b). With the addition of new shells, the number of inner shells which shield the valence electrons from the nucleus increases. In other words, the shielding effect or the screening effect increases.
As a result, the force of attraction of the nucleus for the valence electrons further decreases and hence the ionisation enthalpy should decrease.
(c). Further, in a group from top to bottom nuclear charge increases with increase in atomic number. As a result, the force of attraction of the nucleus for the valence electrons increases and hence the ionisation enthalpy should increase.
The Combined effect fo the increase in atomic size and screening effect more than compensate the effect of the increased nuclear charge. Consequently, the valence electrons become less and less firmly held by the nucleus and hence the ionisation enthalpy gradually decreases as we move down the group.
(i)
Across the period, the nuclear charge increases and the atomic radius decreases As. A result, the tendency of the atom of an element to attract the shared pair of electrons towards itself increases and hence the electronegativity of the element increases e.g., electronegativity of the elements of the 2nd period increases regularly from left to right as follows Li (1,0), Be (1.5), B (2,0) C (2.5), N (3.0), O (3.5) and
(ii)
The lonisation enthalpy decreases regularly as we move from top to bottom, as explained below.
(a). On moving down a group from top to bottom, the atomic size increases gradually due to the addition of a new principal energy shell at each succeeding element. As a result, the distance between the nucleus and the valence shell increases.
In other words, the force the ionisation enthalpy should decrease.
(b). With the addition of new shells, the number of inner shells which shield the valence electrons from the nucleus increases. In other words, the shielding effect or the screening effect increases.
As a result, the force of attraction of the nucleus for the valence electrons further decreases and hence the ionisation enthalpy should decrease.
(c). Further, in a group from top to bottom nuclear charge increases with increase in atomic number. As a result, the force of attraction of the nucleus for the valence electrons increases and hence the ionisation enthalpy should increase.
The Combined effect fo the increase in atomic size and screening effect more than compensate the effect of the increased nuclear charge. Consequently, the valence electrons become less and less firmly held by the nucleus and hence the ionisation enthalpy gradually decreases as we move down the group.
