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Question

Explain the hybridisation taking place in H2O molecule, which is responsible for its bond formation.

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Solution

The electronic configuration of oxygen atom is 1s2 2s2 2p4. Therefore, for bond formation, one s-orbital (2s) and three p-orbitals ( 2px, 2py and 2pz ) intermix and redistribute into four identical sp3 orbitals of equal energies and shape.
This leads to sp3 hybridisation in H2O molecule.

Now we have four sp3 hybridised orbitals, where 2 orbitals already have paired electrons, while 2 orbitals are having single electron each. These 2 sp3 hybridised orbitals having single electron each overlap with s-orbital of 2 hydrogen atoms forming 2 covalent bonds.



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