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Question

Explain the importance of the property of anomalous expansion of water.


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Solution

Anomalous expansion of water:

  • The density of water is 1 g cm-3 at 4°C. Normally, substances expand on heating and contract on cooling. Water also contracts on cooling until the temperature reaches 4°C.
  • However, on further cooling below 4°C, water expands instead of contracting up to 0°C. At 0°C, water has the maximum volume in the form of ice. This unusual and unique property of water is known as anomalous expansion of water.
  • As a result of this property, the density of water is maximum at 4°C. When water is cooled below 4°C, it expands instead of contracting and becomes less dense (or lighter). At 0°C, water freezes to form ice. Due to expansion, the volume of ice at 0°C is more than the volume of water at 4°C. Therefore, the density of ice at 0°C is less than the density of water. That is why ice floats on the surface of the water.

Effects of anomalous expansion of water:

  • In cold regions, where the atmospheric temperature falls to 0°C or below, water on the surface of ponds and lakes cools and freezes into ice.
  • The frozen ice floats on the surface of the water as the density of ice is less than the density of water.
  • As water is a bad conductor of heat, the ice layer prevents the loss of heat from the lower layers of water.
  • Thus, water below the layer of floating ice has temperatures greater than 0°C, which helps in the survival of aquatic life present underneath.

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