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Question

Explain the non-linear shape of H2S and non-planar shape of PCl3 using valence shell electron pair repulsion theory.

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Solution

Central atom of H2 is S. There are 6 electrons in its valence shell (16S = 2, 8, 6). Two electrons are shared with two H-atoms and the remaining four electrons are present as two lone pairs.

Hence, total pairs of electrons are four (2 bond pairs and 2 lone pairs). Due to the presence of 2 lone pairs, the shape becomes bent (non-linear).

The electron pair geometry is Tetrahedral.

PCl3 - Central atom is phosphorus. There are 5 electrons in its valence shell (15 P=2, 8, 5). Three electrons are shared with three Cl-atoms and the remaining two electrons are present as one lone pair.

Hence, total pairs of electrons are four (1 lone pair and 3 bond pairs). Due to the presence of one lone pair, the shape becomes pyramidal (non-planar).


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