Exposure to carbon monoxide (ex., coal gas) is extremely dangerous and can kill a person because -
The compound formed, Carboxyhemoglobin does not allow RBCs to carry out their respiratory function.
Carboxyhemoglobin(COHb) is a stable complex of carbon monoxide and hemoglobin that forms in red blood cells upon contact with carbon monoxide (CO). Large quantities of CO hinder the ability of Hb to deliver oxygen to the body.