Express linkage isomerism in $[C o (N H_{3})_{5} N O_{2}] C l_{2}$ .

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Solution

$N O_{2}$ can bend in two ways either link with nitrogen or with oxygen.

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Q. Which one of the following pairs of isomers and types of isomerism are correctly matched?
(i)

[C o (N H_{3})_{5} (N O_{2})] C l_{2}

and

[C o (N H_{3})_{5} (O N O) C l_{2} . . . (L i n k a g e)

(ii)

[C u (N H_{3})_{4}] [P t C l_{4}]

and

[P t (N H_{3})_{4}] [C u C l_{4}] . . . (C o o r d i n a t i o n)

(iii)

[P t C l_{2} (N H_{3})_{4}] B r_{2}

and

[P t B r_{2} (N H_{3})_{4}] C l_{2} . . . (I o n i z a t i o n)

Select the correct answer using the codes given below:

Q. Draw the structural isomer of

[C o (N H_{3})_{5} N O_{2}] C l_{2}

and name the type of isomerism?

Q. a. Write the IUPAC name of:

[C o (N H_{3})_{4} (H_{2} O) C l] C l_{2}

b. Explain linkage isomerism with example.

Q. Two isomers of

[C o (N H_{3})_{5} (N O_{2})] C l_{2}

differ in colour because of difference in linkage of

N O_{2}

that can show linkage-isomerism.
If true enter 1, else enter 0.

A research guide instructed his two students to synthesize complex $[C o (N H_{3})_{5} (N O_{2})] C l_{2}$

They synthesized the complexes with identical molecular formula, molar mass, geometry, conductance and spin, but they differed in colour. Bases on the above facts the following question.

(i) The difference in colour is due to:

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Express linkage isomerism in [Co(NH3)5NO2]Cl2.

NO2 can bend in two ways either link with nitrogen or with oxygen.

Express linkage isomerism in $[C o (N H_{3})_{5} N O_{2}] C l_{2}$ .

$N O_{2}$ can bend in two ways either link with nitrogen or with oxygen.