We know:
1 km = 1000 m
1 h = (60 60 ) s = 3600 s
Now,
(a) 45 km/h = (45 1000)/(1 3600)
= 12.5 m/s
(b) 135 km/h = (135 1000)/(1 3600)
= 37.5 m/s
(c) 90 km/h = (90 1000)/(1 3600)
= 25 m/s
(d) 75 km/h = (75 1000)/(1 3600)
= 20.83 m/s