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Question

Extra very pure N2 can be obtained by heating:

A
NH3 with CuO
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B
NH4NO3
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C
(NH4)2Cr2O7
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D
Ba(N3)2
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Solution

The correct option is A Ba(N3)2
Very pure nitrogen can be obtained by the thermal decomposition of sodium or barium azide.

2NaN3573K−−2Na+3N2

Azide salt of barium can be obtained in the purest form as well as the decomposition product contains solid Ba as a by-product along with gaseous nitrogen, hence no additional step of separation is required.

Ba(N3)2heatBa+3N2

Hence, option D is correct.

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