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Question

Extraction of gold and silver involves leaching with CN ion. Silver is later recovered by

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A
Zone refining
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B
Liquation
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C
Displacement with Zn
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D
Distilation
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Solution

The correct option is C Displacement with Zn
Zn being more reactive than Ag and Au, displaces them.

From Native ore,
4Ag+8NaCN+2H2O+O2Leaching−−−−4Na[Ag(CN)2]+4NaOH soluble(Sodium dicyanoargentate(I))

2Na[Ag(CN)2]+ZnDisplacement−−−−−−−Na2[Zn(CN)4]+2Ag

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