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Question

Extraction of silver is achieved by initial complexation of the ore (Argentite) with X followed by reduction with Y.X and Y, respectively, are:

A
CN and Zn
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B
CN and Cu
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C
Cl and Zn
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D
Br and Zn
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Solution

The correct option is D CN and Zn
The process of extraction of Silver or Gold is done by the Mac-Arthur Forest process. Where NaCN is used as a reagent and an electropositive metal is added to further take out the pure metal from the complex formed during the reaction as represented by the following reaction.

Ag2S+4NaCN2Na[Ag(CN)2]+Na2S

2Na[Ag(CN)2]+ZnNa2[Zn(CN)4]+2Ag

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