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Byju's Answer
Standard XII
Chemistry
Oxides of Xenon
Fe2+ + 2e- → ...
Question
F
e
2
+
+
2
e
−
→
F
e
;
E
∘
=
−
0.44
V
C
u
2
+
+
2
e
−
→
C
u
;
E
∘
=
+
0.34
V
The
E
∘
of
F
e
+
C
u
2
+
⇋
F
e
2
+
C
u
is _______ and thus, reaction is spontaneous/nonspontaneous.
A
0.78
V
and spontaneous
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B
0.78
V
and nonspontaneous
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C
−
0.78
V
and spontaneous
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D
−
0.78
V
and nonspontaneous
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Solution
The correct option is
A
0.78
V
and spontaneous
F
e
2
+
+
2
e
−
→
F
e
;
E
∘
=
−
0.44
V
-(1)
C
u
2
+
+
2
e
−
→
C
u
;
E
∘
=
+
0.34
V
- (2)
Inverting (1)
F
e
→
F
e
2
+
+
2
e
−
E
∘
=
+
0.44
V
- (3)
Since number of electrons involved in both the reactions are same we can add (2) and (3). On addition,
F
e
+
C
u
2
+
⇋
F
e
2
+
C
u
E
∘
−
+
0.34
V
+
0.44
V
=
0.78
V
△
G
∘
=
−
n
F
E
∘
Since
E
∘
is positive then
△
G
∘
is negative.
When
△
G
∘
is negative, reactions are spontaneous.
Suggest Corrections
0
Similar questions
Q.
Determine whether the following reaction will be spontaneous or nonspontaneous under standard conditions.
Z
n
(
s
)
+
C
u
2
+
(
a
q
)
→
Z
n
2
+
(
a
q
)
+
C
u
(
s
)
,
Δ
H
0
=
−
219
k
J
,
Δ
S
0
=
−
21
J
K
−
1
.
Q.
Δ
G
o
for the reaction,
C
u
2
+
+
F
e
→
F
e
2
+
+
C
u
is:
(Given:
E
o
C
u
2
+
|
C
u
=
+
0.34
V,
E
o
F
e
2
+
|
F
e
=
−
0.44
V).
Q.
E
∘
for
F
e
/
F
e
2
+
is +0.44 V and
E
∘
for
C
u
/
C
u
2
+
is -0.32V. Then, in the cell:
Q.
The reaction
F
e
→
F
e
2
+
+
2
e
−
(
+
0.44
volt
)
would occur spontaneously with which of the following?
I.
P
b
→
P
b
2
+
+
2
e
−
(
+
0.13
volt
)
II.
C
u
→
C
u
2
+
+
2
e
−
(
−
0.34
volt
)
III.
2
A
g
+
+
2
e
−
→
2
A
g
0
(
+
0.80
volt
)
Select the correct option among the following
:
Q.
Which of the following metals, when coupled, will leads to a non-spontaneous cell reaction?
Given:
A
u
+
(
a
q
)
+
e
−
→
A
u
(
s
)
;
E
0
=
1.69
V
C
u
2
+
(
a
q
)
+
2
e
−
→
C
u
(
s
)
;
E
0
=
0.34
V
P
b
2
+
(
a
q
)
+
2
e
−
→
P
b
(
s
)
;
E
0
=
−
0.13
V
F
e
2
+
(
a
q
)
+
2
e
−
→
F
e
(
s
)
;
E
0
=
−
0.44
V
C
a
2
+
(
a
q
)
+
2
e
−
→
C
a
(
s
)
;
E
0
=
−
2.87
V
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