The correct option is C sodium hydroxide
A solution of a Iron salt (Iron ammonium sulphate solution for Fe2+) mixed with an equal amount of another solution, gives a physical change, usually a colour change due to a precipitation of the iron insoluble compound or formation of a complex since iron is a transitional metal. The green / cyan ppt, insoluble in excess formed with sodium hydroxide and carbonate is already a good indication of the presence of Fe2+.