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Question

Ferric alum gives red color with NH4SCN due to formation of:

A
Al(SCN)3
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B
FeSO4
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C
Fe(SCN)3
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D
Fe(SCN)2
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Solution

The correct option is B Fe(SCN)3
Ferric atom has Fe3+ ion which on reaction with NH4SCN gives red color due to formation of the Fe(SCN)3 . When in contact with Fe3+ ion solution in ferric alum solution the product of the reaction is a solution with a blood red colour, due to the formation of the thiocyanato iron complex Fe(SCN)3.

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